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High Purity Hydrogen Fluoride(HF)Specialty Gases

  • DOT Shipping Name Hydrogen Fluoride, Anhydrous
  • DOT Classification 8
  • DOT Label Nonflammable Gas
  • UN Number UN 1790
  • CAS No. 7664-39-3
  • CGA/DISS 660/638

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Specifications 

Purity , % 99.98
Water  ≤ 50 ppmw
Fluorosilicic Acid  ≤ 50 ppmw
Sulfur Dioxide ≤ 30 ppmw
Non-volatile Acid  ≤ 50 ppmw

Technical Information

Cylinder State @ 21.1°C  Liquid
Flammable Limits In Air  Non-flammable 
Auto Ignition Temperature (°C ) -
Molecular Weight (g/mol) 20.01
Specific gravity (air =1) 0.99
Critical Temperature ( °C ) 188
Critical Pressure ( psig ) 2939.3

Description 

Hydrogen fluoride (fluorane) is an inorganic compound with chemical formula HF. It is a very poisonous, colorless gas or liquid that dissolves in water to yield an aqueous solution termed hydrofluoric acid. It is the principal industrial source of fluorine, often in the form of hydrofluoric acid, and is an important feedstock in the preparation of many important compounds including pharmaceuticals and polymers, e.g. polytetrafluoroethylene (PTFE). HF is also widely used in the petrochemical industry as a component of superacids. Due to strong and extensive hydrogen bonding, it boils at near room temperature, much higher than other hydrogen halides.Hydrogen fluoride is an extremely dangerous gas, forming corrosive and penetrating hydrofluoric acid upon contact with moisture. The gas can also cause blindness by rapid destruction of the corneas.

The electrowinning of aluminium relies on the electrolysis of aluminium fluoride in molten cryolite. Several kilograms of HF are consumed per ton of Al produced. Other metal fluorides are produced using HF, including uranium tetrafluoride.HF is the precursor to elemental fluorine, F2, by electrolysis of a solution of HF and potassium bifluoride. HF serves as a catalyst in alkylation processes in refineries. It is used in the majority of the installed linear alkyl benzene production facilities in the world. The process involves dehydrogenation of n-paraffins to olefins, and subsequent reaction with benzene using HF as catalyst.Hydrogen fluoride is an excellent solvent. Reflecting the ability of HF to participate in hydrogen bonding, even proteins and carbohydrates dissolve in HF and can be recovered from it. In contrast, most non-fluoride inorganic chemicals react with HF rather than dissolving.Hydrogen Fluoride is a colorless , nonflammable , and liquefied gas with a penetrating odor .

Applications

● In semiconductor fabrication: native oxide etch from silicon wafers

● In various chemical reactions.

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